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Quantitative analyses are reported for active (N2, CH4, CO, CO2, H2, O2, HF, HCl, H2S, SO2) and noble (He, Ar, Ne) gases released by crushing and step heating of magmatic-hydrothermal alunite from the Tapajós gold province in Brazil. This is the oldest known alunite (40Ar/39Ar age of 1.87 Ga), and because it has undergone minimal postdepositional thermal or tectonic strain, it is excellent ...

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ethanol-washed and weighed pieces of alunite (total 6.96 g), each 0.5 to 1.0 cm on a side, was analyzed in several steps. The sample was crushed off-line in vacuo and returned to the manifold. The fluid was extracted, and its gases were analyzed. The alunite was then heated in the same crush …